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The most important of the endogenous antioxidants are vitamins A and E. This class of compounds functions as an “antioxidant-antibacterial” which reduces free radicals and quenches the effects of reactive oxygen species. The two-fold function of vitamin E is as a chain-breaking antioxidant and as a regulator of cell growth, proliferation, and differentiation. In order to achieve a beneficial result from these activities, levels of vitamin E must be increased (up to about 100 to 1000 ng/ml) in serum. Vitamin E can be stored only in lipidic environments and is typically found in a lipid composition. The hydrophobic or lipophilic character of the vitamin E molecule allows it to distribute into lipid matrices and form a complex with lipids through a self-association process. Typically, the main role of the triglyceride triglycerides consists of the storage of fatty acids and neutral lipids. When exposed to oxygen, (1) lipid peroxidation is initiated, (2) triglycerides are degraded to give fatty acids and glycerol, and (3) the oxidation of fatty acids to volatile aldehydes and ketones. Depending on the types of fatty acids present in the initial mixture and their concentrations, the order of oxidation is shown below: oleic acid (C18:1)>palmitic acid (C16:0)>stearic acid (C18:0). Thus, neutral lipids such as triglycerides and sterol esters, which are composed of fatty acids, are susceptible to photo-oxidation.
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