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my name is bruno dallaqua, i’m a graphic/web designer from southern brazil. i work on the design.enantioselective formation of bispyrrolidinyl piperazine derivatives via imino-diels-alder reaction of 3-azabicyclo[3.3.1]nonanone and n-acetyl-n-methylpyrrolidine-2-carboximidamide. [structure: see text] enantioselective three-component coupling/cyclization reaction of 3-azabicyclo[3.1]nonanone and n-acetyl-n-methylpyrrolidine-2-carboximidamide gives a series of chiral bispyrrolidinyl piperazine derivatives with moderate to excellent enantioselectivity.the new administration in the u.s. is moving quickly. president obama’s new team in washington wants its ideas to have an impact on how our lives work by the end of the year. so we’re asking you to help provide “reality check” where necessary. we do so by asking for your feedback on several key issues being deliberated in congress. like most people, we use our phones and computers on a daily basis to send and receive texts, emails and other messages. the intersection of technology and the workplace is a vast and growing one and this issue is central to the union’s mission of building a stronger middle class, more equal and more secure. this issue is also a major concern for the communications workers of america (cwa), one of the nation’s largest and most successful unions with over 1.5 million members. americans spend more time on their phones than watching television, and their quality of life has been increasingly tied to the performance and reliability of the products they use. under the leadership of cwa president larry cohen, our union has been working on emerging issues for decades — from fighting for a “breakthrough” cellphone technology that serves union members to having weathered the collapse of the telecom industry. during his term, cohen and the union have tried to educate consumers about the perils of the unlimited-data plans that are so popular now. but, we also recognize that employers are demanding an increasing amount of data from workers, for example, by asking for constant updates on everyone’s social-media sites. we’re also mindful that students are being taught by their teachers to use phones and tablets to stay up-to-date with their online courses and the virtual reality headsets that are already being developed to enhance and speed up some forms of education. our message: it’s not only an issue for unions and employees. that should be a bigger part of your life, because all families — and employers — are involved when we take for granted what it means for people to have the best possible access to information at all times. beyond that, it’s a workers’ issue too. cwa is not the only union bringing the issue of smartphones and wireless to the table.
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